H2O2 activation with biomimetic non-haem iron complexes and AcOH: connecting the g = 2.7 EPR signal with a visible chromophore

Chem. Commun., 2014, 50,645-648
DOI: 10.1039/C3CC47632D, Communication

Olga V. Makhlynets, Williamson N. Oloo, Yurii S. Moroz, Irina G. Belaya, Taryn D. Palluccio, Alexander S. Filatov, Peter Muller, Matthew A. Cranswick, Lawrence Que, Elena V. Rybak-Akimova
Mechanistic studies revealed a new S = 1/2 intermediate ([small lambda]_max = 465 nm) in the reaction of electron-rich aminopyridine Fe(II) complexes with H₂O₂/HOAc.
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