Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to [small alpha],[small beta],[gamma],[small delta]-unsaturated sulfonic esters: controlling regioselectivity by rational selection of electron-withdrawing groups

Chem. Commun., 2014, 50,698-700
DOI: 10.1039/C3CC46290K, Communication

Junzhu Lu, Jinxing Ye, Wei-Liang Duan
Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to electron-deficient dienes was developed through rational selection of electron-withdrawing groups on the dienes, furnishing chiral phosphine derivatives in high ee.
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