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A Stable, Mononuclear, Cationic Pt(III) Complex Stabilised by Bulky N-Heterocyclic Carbenes

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC48553F, Communication
Salvador Conejero, Agustin Lledos, Orestes Rivada-Wheelaghan, Manuel Angel Ortuno, Sergio E Garcia-Garrido, Pablo Javier Alonso, Josefina Diez
The thermally stable, paramagnetic Pt(III) complex [PtI2(IPr)2][BArF] has been prepared by oxidation of the Pt(II) complex [PtI2(IPr)2] with iodine in the presence of NaBArF. X-ray crystallographic studies revealed the mononuclear...
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