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Antiaromatic planar cyclooctatetraene: a strategy for developing ambipolar semiconductors for field effect transistors

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Chem. Commun., 2013, 49,5354-5356
DOI: 10.1039/C3CC41764F, Communication
Tohru Nishinaga, Takeshi Ohmae, Kazunari Aita, Masayoshi Takase, Masahiko Iyoda, Tatsuya Arai, Yoshihito Kunugi
A single crystal FET device of sulphur-bridged tetrathienylene bearing the antiaromatic COT core and radially [small pi]-extended with TIPS-ethynyl substituents showed ambipolar characteristics with high and balanced hole and electron mobilities.
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