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Chiral microporous Ti(salan)-based metal-organic frameworks for asymmetric sulfoxidation

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Chem. Commun., 2013, 49,7120-7122
DOI: 10.1039/C3CC43225D, Communication
Chengfeng Zhu, Xu Chen, Zhiwei Yang, Xia Du, Yan Liu, Yong Cui
Chiral microporous metal-metallosalan frameworks are constructed from a multi-functionalized bridging chiral (Ti)salan ligand and the frameworks are shown to be efficient and recyclable heterogeneous catalysts for the oxidation of thioethers to sulfoxides by aqueous H2O2.
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