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Monitoring the on-off switching of the electronic communication in diethynylplatinum(II)-bridged dyads using triplet energy transfer

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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC42634C, Communication
Ahmed M. Soliman, Mohammed Abdelhameed, Eli Zysman-Colman, Pierre D. Harvey
Despite conjugation and downhill manifolds in [Ir]-[Pt]-[ZnTPP] ([ZnTPP] = (tetraphenylporphyrin)zinc(II), [Ir] = bis(phenylpyridinato)(bipyridine)iridium(III), [Pt] = trans-C[triple bond, length as m-dash]CPt(PBu3)2-C[triple bond, length as m-dash]C), essentially no T1[Ir] [rightward arrow] S1/T1[ZnTTP] energy transfer occurs.
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