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Reaction of strongly electrophilic alkenylboranes with phosphanylalkynes: rare examples of intermolecular 1,1-alkenylboration reactions

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Chem. Commun., 2013, 49,6992-6994
DOI: 10.1039/C3CC43294G, Communication
Olga Ekkert, Ottmar Tuschewitzki, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker
Simple alkenylbis(pentafluorophenyl)boranes undergo 1,1-alkenylboration with phosphanylacetylenes to give phosphane-borane Lewis pairs with a conjugated diene backbone.
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