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First asymmetric synthesis of planar chiral [2.2]metacyclophanes

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Chem. Commun., 2013, 49,6125-6127
DOI: 10.1039/C3CC42275E, Communication
Marco Blangetti, Helge Muller-Bunz, Donal F. O'Shea
A general three step asymmetric synthesis of planar chiral [2.2]metacyclophanes utilizing selective benzylic and aryl metalations is described.
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