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Microporous metal-organic open framework containing uncoordinated carbonyl groups as postsynthetic modification sites for cation exchange and Tb3+ sensor

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC43168A, Communication
Jianwei Cao, yanfei gao, Yanqin Wang, Chunfang Du, Zhiliang Liu
A novel 3D microporous compound [Zn3(Httca)2(4,4'-bpy)(H2O)2]n (MOF-COOH) containing uncoordinated carbonyl groups pointing to the pores was prepared. The uncoordinated carbonyl groups in the channels can act as postsynthetic modification sites...
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