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Benzyne-benzyne-RNC or CO triple sequential insertion into the Pd-C bond: synthesis of ten-membered N-heterocycles through stable ten- and eleven-membered palladacycles

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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC43049A, Communication
Maria-Jose Oliva-Madrid, Isabel Saura-Llamas, Delia Bautista, Jose Vicente
The first double insertion of benzyne into a M-C bond and the synthesis of ten-membered tribenzazecine derivatives of homoveratrylamine by further insertion of CO or RNC into the Pd-C bond.
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