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Copper-mediated controlled radical polymerization under biological conditions: SET-LRP in blood serum

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC43731K, Communication
David Haddleton, Qiang Zhang, Paul Wilson, Zaidong Li
The polymerization of hydrophilic monomers is reported utilizing Cu(0)-mediated living radical polymerization, SET-LRP. Highly active Cu(0) is formed in-situ as a result of rapid disproportionation of [Cu(I)(Me6-Tren)Br]. Disproportionation and homogenous...
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