Dibenzyl and diallyl 2,6-bisiminopyridinezinc(II) complexes: Selective alkyl migration to the pyridine ring leads to remarkably stable dihydro-pyridinates.

Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC42798F, Communication

John J. Sandoval, Pilar Palma, Eleuterio Alvarez, Antonio Rodriguez-Delgado, Juan Campora
Diorganozinc compounds (ZnR2) with R = CH2Ph or CH2CH=CH2 react with 2,6-bisiiminopyrdines (iPrBIP) to afford thermally stable dihydropyridinate(-1) complexes, and do not react if R = CH2SiMe3 or CH2CMe2Ph. NMR...
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