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Ferromagnetic superexchange in a 1D -[LaIII-radical]- coordination polymer

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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC43267J, Communication
Elisabeth M. Fatila, Rodolphe Clerac, Mathieu Rouzieres, Dmitriy V. Soldatov, Michael Jennings, Kathryn E. Preuss
The -[La(hfac)3-boaDTDA]n- coordination polymer exhibits ferromagnetic (FM) coupling between the radicals, mediated through the diamagnetic LaIII ion. The lanthanum 6s orbital cannot be solely responsible for the superexchange mechanism.
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