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Natural and Magnetic Optical Activity of 2-D Chiral Cyanido-Bridged MnII-NbIV Molecular Ferrimagnets

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC43195A, Communication
Szymon Chorazy, Robert Podgajny, Wojciech Nitek, Tomasz Fic, Edward Goerlich, Michal Rams, Barbara Sieklucka
Unique two dimensional enantiopure cyanido-bridged {MnII(R-mpm)2[NbIV(CN)8]}[round bullet, filled]4H2O (1-R) and {MnII(S-mpm)2 [NbIV(CN)8]}[round bullet, filled]4H2O (1-S) (mpm = [small alpha]-methyl-2-pyridine-methanol) ferrimagnets with Tc = 23.5 K were synthesized and characterized. They reveal natural optical activity (NOA)...
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