Charge Transfer Phase Transition with Reversed Thermal Hysteresis Loop in the Mixed-Valence Fe9[W(CN)8]6∙xMeOH Cluster

Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C3CC48029A, Communication

Szymon Chorazy, Robert Podgajny, Wojciech Nogas, Wojciech Nitek, Marcin Koziel, Michal Rams, Ewa JUSZYNSKA, Jan Zukrowski, Czeslaw Kapusta, Koji Nakabayashi, Takashi Fujimoto, Shin-ichi Ohkoshi, Barbara Sieklucka
Bimetallic pentadecanuclear cyanido-bridged {Fe9[W(CN)8]6 (MeOH)24}[round bullet, filled]xMeOH cluster of a FeII/III-WIV/V mixed valence nature reveals a reversible single-crystal-to-single-crystal transformation concomitant with metal-to-metal charge transfer between Fe and W ions. The dominance of...
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