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A dual site catalyst for mild, selective nitrile reduction

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Chem. Commun., 2014, Advance Article
DOI: 10.1039/C3CC47384H, Communication
Zhiyao Lu, Travis J. Williams
A novel ruthenium bis(pyrazolyl)borate catalyst exhibits useful reactivity in ammonia borane dehydrogenation and water oxidation. It also enables unprecedented cooperative reduction reactivity in which boron and ruthenium centers work in concert to effect surprisingly selective nitrile reduction.
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