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Non-covalent self assembly controls the relaxivity of magnetically active guests

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Chem. Commun., 2014, 50,1375-1377
DOI: 10.1039/C3CC48389D, Communication
Vincent Li, Yoo-Jin Ghang, Richard J. Hooley, Travis J. Williams
The relaxivity of a magnetically responsive Gd complex can be controlled by non-covalent molecular recognition with a water-soluble deep cavitand. Lowered relaxivity is conferred by a self-assembled micellar "off state", and the contrast can be regenerated by addition of a superior guest.
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