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Rhodium(I)-Catalyzed N-CN Bond Cleavage: Intramolecular [small beta]-Cyanation of Styrenes

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC43597K, Communication
Rui Wang, John Falck
We report an unprecedented rhodium(I)-catalyzed N-CN bond cleavage and its application in an intramolecular [small beta]-cyanation of styrenes that affords arylacrylonitriles (cinnamonitriles) in good yields. The overall process represents a rare...
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