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An unprecedented Pd-catalyzed trans-addition of boronic acids to ynamides

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Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C3CC49069F, Communication
Yuanfa Yang, Lina Wang, Jieni Zhang, Yali Jin, Gangguo Zhu
An unprecedented Pd-catalyzed trans-addition of boronic acids to ynamides has been reported, giving [small alpha],[small beta]-disubstituted enamides in high yields with excellent regio- and stereoselectivity. A possible mechanism involving the palladium carbene...
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