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An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion

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Chem. Commun., 2014, Advance Article
DOI: 10.1039/C3CC48782B, Communication
Atsutoshi Yokoyama, Jung Eun Han, Kenneth D. Karlin, Wonwoo Nam
Reaction of a nonheme iron(III)-peroxo complex, [FeIII(14-TMC)(O2)]+, with NO+ affords an iron(IV)-oxo complex, [FeIV(14-TMC)(O)]2+, and nitrogen dioxide (NO2), followed by conversion to the nitrato complex, [FeIII(14-TMC)(NO3)(F)]+.
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