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Near infrared photolysis of a Ru polypyridyl complex by upconverting nanoparticles

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Chem. Commun., 2014, Advance Article
DOI: 10.1039/C3CC47601D, Communication
E. Ruggiero, A. Habtemariam, L. Yate, J. C. Mareque-Rivas, L. Salassa
NaYF4:Yb3+/Er3+nanocrystals upconvert near infrared light (980 nm) into higher energy visible photons capable of effecting the photodissociation of the monodentate pyridyl ligand in cis-[Ru(bpy)2(py)2]Cl2: opening an opportunity for advancing the use of photoactivatable metal complexes in medicine and biology.
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