An unexpected stereoisomerism in enantiomerically pure trisadducts of C60 with the inherently chiral trans-3,trans-3,trans-3 addition pattern

Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC48941H, Communication

Maria Riala, Nikos Chronakis
We have synthesized and isolated two C₂-symmetric enantiomerically pure trisadducts of C₆₀ with the inherently chiral trans-3,trans-3,trans-3 addition pattern with the aid of an enantiopure cyclo-trismalonate tether. An unexpected stereoisomerism...
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