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Enhancement of spin-crossover cooperativity mediated by lone pair-[small pi] interactions and halogen bonding

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Chem. Commun., 2014, 50,1003-1005
DOI: 10.1039/C3CC48334G, Communication
Nassim Nassirinia, Saeid Amani, Simon J. Teat, Olivier Roubeau, Patrick Gamez
Rational ligand design has allowed the generation of a highly cooperative spin-transition iron(II) complex, an unprecedented result in the family of (2,2[prime or minute]-dipyridylamino/s-triazine)-based SCO materials.
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