Structural analysis and reactivity of unusual tetrahedral intermediates enabled by SmI2-mediated reduction of barbituric acids: vinylogous N-acyliminium additions to alpha-alkoxy-N-acyl-carbamides

Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC48932A, Communication

Michal Szostak, Brice Sautier, David John Procter
Structural characterisation and reactivity of new tetrahedral intermediates based on a highly modular barbituric acid scaffold, formed via chemoselective electron transfer using the SmI2-H2O reagent, is reported. Lewis acid promoted...
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