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Synthesis of 3-((trifluoromethyl)thio)indoles via a reaction of 2-alkynylaniline with trifluoromethanesulfanylamide

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Chem. Commun., 2014, 50,578-580
DOI: 10.1039/C3CC45958F, Communication
Jie Sheng, Shaoyu Li, Jie Wu
3-((Trifluoromethyl)thio)indoles can be synthesized by a palladium(II)-catalyzed reaction of 2-alkynylaniline with trifluoromethanesulfanylamide in the presence of bismuth(III) chloride.
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