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Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)-OOH species and a copper mediated NO reductive coupling reaction

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Chem. Commun., 2014, Advance Article
DOI: 10.1039/C3CC47942K, Communication
Sunghee Kim, Maxime A. Siegler, Kenneth D. Karlin
New peroxynitrite-copper chemistry ensues via addition of [radical dot]NO(g) to a CuII-hydroperoxo species; the ligand-Cu(I) complex was shown to effect [radical dot]NO(g) reductive coupling.
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