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E-H (E = R3Si or H) bond activation by B(C6F5)3 and heteroarenes; competitive dehydrosilylation, hydrosilylation and hydrogenation

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Chem. Commun., 2014, Advance Article
DOI: 10.1039/C3CC47372D, Communication
Liam D. Curless, Ewan R. Clark, Jay J. Dunsford, Michael J. Ingleson
Addition of R3Si-H-B(C6F5)3 to heteroarenes leads to surprisingly complex and substrate dependent mixtures due to competing dehydrosilylation, hydrosilylation and hydrogenation.
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