Sandwich Complex with Axial Symmetry for Harnessing the Anisotropy in a Prolate Erbium(III) Ion.

Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC48557A, Communication

Jennfier J Le Roy, Ilia Korobkov, Muralee Murugesu
A mononuclear ErIII sandwich type complex, [Li(DME)3][ErIII(COT")2], was isolated using 1,4-bis(trimethylsilyl)cyclooctatetraenyl dianion (COT"). Remarkably, this low-symmetry complex exhibits magnet-like behavior of magnetic remanence and coercivity in the hysteresis loops up...
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