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Making syngas electrocatalytically using a polypyridyl ruthenium catalyst

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Chem. Commun., 2014, 50,335-337
DOI: 10.1039/C3CC47251E, Communication
Zuofeng Chen, Peng Kang, Ming-Tian Zhang, Thomas J. Meyer
In acetonitrile solutions saturated in CO2 with added water and weak acid, the polypyridyl complex [Ru(tpy)(bpy)(NCCH3)]2+ acts as an electrocatalyst for the formation of syngas mixtures of H2 and CO.
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