Stabilisation of mu-peroxido bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC48196D, Communication

Josef Pap, Apparao Draksharapu, Michel Giorgi, Wesley Browne, Jozsef Kaizer, Gabor Speier
The spectroscopic characterisation of (mu-1,2-peroxido)diiron(III) species formed transiently upon reaction of [Fe(II)(NN)3]2+ complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in...
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