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Strongly Donor Metalla-N-Heterocyclic Carbenes

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC47987K, Communication
Javier Ruiz, Lucia Garcia, Carmen Mejuto, Marilin Vivanco, Maria Rosario Diaz, Santiago Garcia-Granda
By choosing the appropriate coupling reactions an isocyanide ligand in complex [Fe(Cp)(CO)(CNXylyl)2]+ is transformed either into a conventional NHC or into a metalla-N-heterocyclic carbene (MNHC), with CO and CNR ligands...
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