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Ruthenium-Catalyzed ortho-C-H Halogenations of Benzamides

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC47852A, Communication
Lutz Ackermann, Lianhui Wang
[Ru3(CO)12] and AgO2C(1-Ad) enabled first ruthenium-catalyzed intermolecular halogenations of arenes via C-H activation. Thereby, brominations and iodinations of electron-rich and electron-deficient benzamides were achieved in a highly selective fashion.
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