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Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity

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Chem. Commun., 2014, Advance Article
DOI: 10.1039/C3CC46574H, Communication
Xiao-Fei Yang, Xiao-Hui Li, Chang-Hua Ding, Chao-Fan Xu, Li-Xin Dai, Xue-Long Hou
A highly regioselective palladium-catalyzed allylic alkylation of dienyl esters with nitromethane has been developed, providing selective access to the C-5 attacked products.
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