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Desymmetrization of cyclic olefins via asymmetric Heck reaction and hydroarylation

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Chem. Commun., 2013, 49,11758-11760
DOI: 10.1039/C3CC47551D, Communication
Sijia Liu, Jianrong (Steve) Zhou
A bisphosphine oxide is uniquely selective as supporting ligand in Pd-catalyzed asymmetric Heck reaction of substituted cyclic olefins and in asymmetric hydroarylation of norbornene.
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