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From dense monomer salt crystals to CO2 selective microporous polyimides via solid-state polymerization

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Chem. Commun., 2014, Advance Article
DOI: 10.1039/C3CC47674J, Communication
Miriam M. Unterlass, Franziska Emmerling, Markus Antonietti, Jens Weber
Solid-state polymerization of crystalline monomer salts yielding CO2 selective polyimides was performed. Identical polyimide copies of the salt crystallite habits are obtained. The polycondensation leads to a porosity well suited for CO2: sorption measurements and IAST calculations show that the polyimides depict a considerable CO2 over N2 selectivity.
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