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Boron-trihalide-promoted Regioselective Ring-opening Reactions of gem-Difluorocyclopropyl Ketones

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC47879C, Communication
Tang-Po Yang, Qiang Li, Jin-Hong Lin, Ji-Chang Xiao
Boron trihalide-promoted ring-opening reactions of gem-difluorocyclopropyl ketones to give the corresponding [small beta]-trifluoromethyl ketones and [small beta]-halodifluoromethyl ketones were described. It was found that boron trihalides act as both Lewis acids and...
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