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Reactions of a Zn(I) complex with group 14 azides - formation of zinc azide and zinc hexazene complexes

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Chem. Commun., 2014, Advance Article
DOI: 10.1039/C3CC47687A, Communication
S. Gondzik, S. Schulz, D. Blaser, C. Wolper, R. Haack, G. Jansen
Reactions of Mesnacnac2Zn2 with group 14 azides either yield the zinc azide [LZn([small mu ]-N3)]2 (2) or zinc hexazene complexes L2Zn2([small mu ]-1,6-R2-N6) (R = Ph 3, Dipp = 2,6-i-Pr2C6H34).
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