Chem. Commun., 2013, 49,11527-11529
DOI: 10.1039/C3CC46555A, Communication
DOI: 10.1039/C3CC46555A, Communication
Monika Vogt, Chao Wu, Allen G. Oliver, Christopher J. Meyer, William F. Schneider, Brandon L. Ashfeld
Herein, we report experimental and computational results for the carboxylation of abnormal anionic N-heterocyclic dicarbenes (NHDCs) with CO2. Under ambient dosing conditions, carbonyl addition occurs selectively at C4 without a second carboxylation event occurring at the C2 carbene center.
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Herein, we report experimental and computational results for the carboxylation of abnormal anionic N-heterocyclic dicarbenes (NHDCs) with CO2. Under ambient dosing conditions, carbonyl addition occurs selectively at C4 without a second carboxylation event occurring at the C2 carbene center.
The content of this RSS Feed (c) The Royal Society of Chemistry