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A mechanistic investigation of hydrodehalogenation using ESI-MS

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Chem. Commun., 2013, 49,11488-11490
DOI: 10.1039/C3CC46271D, Communication
Zohrab Ahmadi, J. Scott McIndoe
The rate of hydrodehalogenation of aryl iodides with a palladium catalyst in methanol exhibits a strong primary kinetic isotope effect from both CD3OD and CH3OD, suggesting that deprotonation plays a major role in the mechanism.
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