Catalytic Stereodivergent Functionalization of H2@C60

Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC46999A, Communication

Enrique E. Maroto, Marta Izquierdo, Michihisa Murata, Salvatorre Filippone, Koichi Komatsu, Yasujiro Murata, Nazario Martin
A complete stereocontrol of 1,3-dipolar cycloaddition of N-metalated azomethine ylides onto endohedral fullerene H₂@C₆₀ is reported for the first time. The stereodivergent synthesis of either the cis or the trans...
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