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A three-dimensional [small pi]-electron acceptor, tri-phenyl-o-carborane, bearing a rigid conformation with end-on phenyl units

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Chem. Commun., 2013, 49,9398-9400
DOI: 10.1039/C3CC45313H, Communication
Guo Fan Jin, Jo-Hyun Hwang, Jong-Dae Lee, Kyung-Ryang Wee, Il-Hwan Suh, Sang Ook Kang
The electronic state of 1,2-diphenyl-o-carborane is altered by B-phenylation through a favorable electronic interaction between the two adjoining phenyl and cage carbon orbitals.
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