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Reactions of d0 tungsten alkylidyne complexes with O2 or H2O. Formation of an oxo siloxy complex through unusual silyl migrations

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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC46014B, Communication
Laurel A. Morton, Maozhong Miao, Tabitha M. Callaway, Tianniu Chen, Shu-Jian Chen, Albert A. Tuinman, Xianghua Yu, Zheng Lu, Zi-Ling Xue
Unusual SiMe3 migrations occur, yielding the OSiMe3 ligand, in the reactions of O2 with (Me3SiCH2)3(Me3SiC[triple bond, length as m-dash])W←O[double bond, length as m-dash]PMe3 as well as H2O with (Me3SiCH2)3W[triple bond, length as m-dash]CSiMe3.
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