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Heterolytic H2 activation on a carbene-ligated rhodathiaborane promoted by isonido-nido cage opening

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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC45880F, Communication
Beatriz Calvo, Ramon Macias, Victor Polo, Maria Jose Artigas, Fernando J. Lahoz, Luis A. Oro
Heterolytic H2 splitting occurs on a carbene-ligated rhodathiaborane that features metal-thiaborane bifunctional synergistic effects, driven by cluster isonido-nido structural fluxionality.
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