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Polyaminoborane main chain scission using N-heterocyclic carbenes; formation of donor-stabilised monomeric aminoboranes

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Chem. Commun., 2013, 49,9098-9100
DOI: 10.1039/C3CC44373F, Communication
Naomi E. Stubbs, Titel Jurca, Erin M. Leitao, Christopher H. Woodall, Ian Manners
The reaction of N-heterocyclic carbenes with polyaminoboranes at 20 [degree]C led to depolymerisation and the formation of labile, monomeric aminoborane-NHC adducts.
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