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Synthesis and properties of boron complexes of [14]triphyrins(2.1.1)

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Chem. Commun., 2013, 49,8955-8957
DOI: 10.1039/C3CC44788J, Communication
Daiki Kuzuhara, ZhaoLi Xue, Shigeki Mori, Tetsuo Okujima, Hidemitsu Uno, Naoki Aratani, Hiroko Yamada
Boron complexes of [14]triphyrins(2.1.1) were prepared from free-base [14]triphyrins(2.1.1) with BPhCl2. The absorption spectrum of the meso-free [small beta]-alkyl-triphyrin boron complex in CH2Cl2 showed a broad weak band at around 640 nm assigned to transition from B-phenyl to the triphyrin.
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