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Mild uncatalyzed hydroamination of an electrophilic alkyne, ethynylcobalticinium

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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC42211A, Communication
Yanlan Wang, Amalia Rapakousiou, Camille Latouche, Jean-Claude Daran, Anu Singh, Isabelle Ledoux-Rak, Jaime Ruiz, Jean-Yves Saillard, Didier Astruc
A fully "green" reaction, the mild uncatalyzed hydroamination of ethynylcobalticinium, produces "push-pull" electrochromic cobalticinium trans-enamines applicable to nanomaterial functionalization.
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