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Al-H [sigma]-bond coordination: expanded ring carbene adducts of AlH3 as neutral bi- and tri-functional donor ligands

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Chem. Commun., 2013, 49,5547-5549
DOI: 10.1039/C3CC42342E, Communication
Joseph A. B. Abdalla, Ian M. Riddlestone, Remi Tirfoin, Nicholas Phillips, Joshua I. Bates, Simon Aldridge
Thermally robust expanded ring carbene adducts of AlH3 have been synthesized with a view to probing their ligating abilities via Al-H [sigma]-bond coordination.
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