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Highly diastereoselective synthesis of chiral aminophenolate zinc complexes and isoselective polymerization of rac-lactide

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Chem. Commun., 2013, 49,8686-8688
DOI: 10.1039/C3CC44980G, Communication
Haobing Wang, Haiyan Ma
A novel enantiopure zinc complex supported by an aminophenolate ligand with multiple stereogenic centers has been diastereoselectively synthesized, which displays excellent isoselectivity in the ring-opening polymerization of rac-lactide to afford stereoblock polylactides with high melting point.
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