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Heterolytic H2 activation on a carbene-ligated rhodathiaborane promoted by isonido-nido cage opening

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC45880F, Communication
Ramon Macias, Beatriz Calvo, Victor Polo, Maria Jose Artigas, F J Lahoz, Luis A Oro
A new mechanism of H2 activation is reported to occur on a carbene-ligated rhodatiaborane that features metal / thiaborane bifunctional synergistic effects. The key is the creation of vacant coordination...
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