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Mechanochemical and silica gel-mediated formation of highly electron-poor 1-cyanocarbonylferrocene

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC44619K, Communication
ISABEL CUADRADO, Daniel Nieto, Sonia Bruna, Ana M[a] Gonzalez-Vadillo, Josefina Perles, M. Merced Montero-Campillo, Mo Otilia, Julia Mendez
Simple manual grinding of solid cyanomethylferrrocene (1) and silica gel provides a facile one-pot access route to unexpected and highly electron-poor metallocene, 1-cyanocarbonylferrocene (2). Electrochemical measurements supported by computational studies...
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